Name | Gadolinium Oxide |
Synonyms | Gadolinium Oxide Gadolinium oxide oxygen(-2) anion Gadolinium(Ⅲ) oxide Gadolinium(III)oxide gadolinium(+3) cation Digadolinium trioxide oxygen(-2) dihydride anion |
CAS | 11129-31-0 12064-62-9 |
EINECS | 235-060-9 |
InChI | InChI=1/2Gd.3H2O/h;;3*1H2/q2*+3;3*-2 |
Molecular Formula | Gd2O3 |
Molar Mass | 362.5 |
Melting Point | 1900℃ |
Water Solubility | insoluble |
Appearance | White crystalline powder |
Storage Condition | Room Temprature |
Sensitive | Easily absorbing moisture |
MDL | MFCD00011026 |
Use | Used as a neutron absorbing material in the atomic reactor, and used as a phosphor and magnetic material additives |
Hazard Symbols | Xi - Irritant |
Risk Codes | R36 - Irritating to the eyes |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S39 - Wear eye / face protection. |
Raw Materials | Samarium |
Reference Show more | 1. Liu Ziqi, Xing Zhihua, Jiang Jingwen, et al. Preliminary Study on Anti-gouty Arthritis Activity and Mechanism of Puerarin-Gadolinium [J]. Journal of Harbin University of Commerce: Natural Science Edition, 2019, 035(001):6-11. 2. Ma Yuchang, Xing Zhihua, Yang Xin, etc. research on antigouty arthritis activity of puerarin-rare earth complex [J]. journal of harbin university of commerce (natural science edition), 2018, v.34;No.151(02):14-18. 3. [IF = 9.229] Qi Sun et al."Theranostic Nanoplatform: Triple-Modal Imaging-Guided Synergistic Cancer Therapy Based on Liposome-Conjugated Mesoporous Silicon Nanoparticles." Acpplmater Inter. 2018;10(2):1963-1975 |
Use | Used as a material for absorbing neutrons in atomic reactors, and used as phosphors and magnetic material additives, etc. |
White amorphous powder. Monoclinic and cubic structures with rare earth sesquioxide. di5 7.407; Melting point 2339 ℃; Boiling point 3900 ℃. Insoluble in water, soluble in organic acids, in the air can absorb water and carbon dioxide. Upon interaction with ammonia, the gadolinium hydrate precipitates.
extraction method: the rare earth chloride solution obtained by processing monazite or mixed rare earth ore is extracted with Pz 04-kerosene-HCI-RCl3 system, first Nd-samarium grouping is carried out, and the raffinate is used to further extract light rare earth, samarium and heavy rare earth were extracted into the organic phase and then used 2. The heavy rare earth was back-extracted with Omol/L HC1 to obtain the medium rare earth samarium gadolinium enrichment, which was reduced by zinc powder. After The europium was extracted by alkalinity method, the mixed rare earth grouping method was used to dissolve the samarium mixed rare earth, gadolinium oxide was prepared by oxalic acid precipitation, separation, drying and burning.
gadolinium oxide is specially used as a component of high refractive index glass in the glass industry. Gadolinium oxide is used together with lanthanum, which contributes to the change of glass glass region and improves the thermal stability of glass. The nuclear industry is used for nuclear reactor control rods, neutron absorbing materials in atomic reactors, magnetic bubble materials, intensifying screen materials, etc. Gadolinium oxide can also be used in the fabrication of capacitors, X-ray screens, and gadolinium gallium garnet materials.
inhalation of gadolinium-containing dust resulted in occupational pneumoconiosis. Staff should be protected. Store in a ventilated, dry place. Should pay attention to moisture, to prevent packaging damage.